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1844
Hancock in England and Goodyear in USA perfect the vulcanisation
of rubber
1854
Peek produces union cases for photographs by mixing shellac
and wood filler and compression moulding the mixture.
1862
UK: Parkes exhibits Parkensine, made from cellulose nitrate,
at the Crystal Palace International Exhibition.
1868
USA: Hyatt brothers produce celluloid from cellulose nitrate
mixed with camphor.
1897
Germany: Spitteler patents casein marketed as galalith or
erinol - made from protein from milk mixed with formaldehyde.
1907
June 20th. Leo Baekeland produces phenol formaldehyde, the
first truly synthetic plastic. (Bakelite).

1912
Klatte patents manufacturing process for PVC.
1927
Germany: Rohm tries to stick two sheets of glass together
using an acrylic ester. Accidentally he discovers safety glass.
1933
ICI (almost by accident) discover polyethylene, marketed as
polythene
1935
DuPont make hexamethylenediamine, which they decide to rename
nylon.
1936
Polymethyl methacrylate (Acrylic) is commercially produced
by ICI
1936
Germany: Wulff brothers produce Polystyrene commercially
1937
Otto Bayer patents polyurethane 1938
Plunkett working for DuPont accidentally discovers polytetrafluroethylene,
PTFE 1943 Silicone is invented
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THE
UNIQUE HISTORY OF PLASTIC
Unknown
to most people, plastic has been around since 1839. It was invented
in the year 1813 by a Mr. Alexander Parks - who was born in Birmingham,
England. Since then it has been used to create all kinds of things,
from children's toys, telephones and radios to the high quality
building materials we see around us today.

The
roots of the invention of PVC go back over 100 years. German entrepreneurs
were attempting to light people's homes with lamps fueled by acetylene
gas. By the time the process was perfected new efficient electric
generators were developed The price of electric lighting dropped
to the point that the acetylene lamp system was too expensive, leaving
a huge stock of acetylene.
In
1912 a German chemist, Fritz Klatte reacted acetylene with hydrochloric
acid (HCl) - a reaction that produced vinyl chloride. At that time
this had no particular use, so it was shelved, where it polymerized
over time. Not knowing what to do with the PVC he had just invented,
he told his bosses at his company, Greisheim Electron, who had the
material patented in Germany. Greisheim Electron failed to find
a useful way to develop the product, and in 1925 their patent expired.
In
1926 an American chemist, Waldo Semon was working at B.F. Goodrich
when he independently invented PVC. Unlike the German chemists,
it dawned on him that this new material would make a perfect shower
curtain. He and his employers at B.F. Goodrich patented PVC in the
United States (Klatte's bosses apparently never filed for a patent
outside Germany) and entered mass production.
It
wasn't until the 1950s that very large quantities of PVC-u were
produced by manufacturers in Germany and the USA. In Germany huge
steps were taken in the use of plastic in the manufacture of windows,
and in 1940s Germany PVC windows were becoming commonplace.
Today
the whole of Europe is fitting PVC-u windows to their buildings,
and in North America large quantities of windows are now made this
way, a quantity increasing rapidly year after year.
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